统计热力学专项课程

Statistical Thermodynamics

本课专为那些在先进领域工作的人设计,如燃烧,高温气体动力学,环境科学,或材料加工,或有人希望总体了解相关领域先进的实验诊断技术。

科罗拉多大学波德分校

Coursera

物理工程

难(高级)

3 个月

本课程由Coursera和Linkshare共同提供
  • 英语
  • 291

课程概况

This specialization is designed for those working in advanced fields such as combustion, high temperature gas dynamics, environmental sciences, or materials processing, or someone who wishes to build a background for understanding advanced experimental diagnostic techniques in these or similar fields.

你将学到什么

Understand how the microscopic properties of atoms and molecules relate to classical thermodynamic properties and to some non-equilibrium phenomena.

Analyze and estimate how thermodynamic materials behave and obtain appropriate equilibrium and non-equilibrium properties.

Apply some computational skills to statistical thermodynamics.

包含课程

课程1
Fundamentals of Macroscopic and Microscopic Thermodynamics

Course 1 first explores the basics of both macroscopic and microscopic thermodynamics from a postulatory point of view. In this view, the meaning of temperature, thermodynamic pressure and chemical potential are especially clear and easy to understand. In addition , the development of the Fundamental Relation and its various transformations leads to a clear path to property relations and to the concept of ensembles needed to understand the relationship between atomic and molecular structural properties and macroscopic properties. We then explore the relationship between atomic and molecular structure and macroscopic properties by taking a statistical point of view. Using a postulatory approach, the method for doing this is made clear. This leads to the development of the partition function which describes the distribution of molecular quantum states as a function of the independent, macroscopic thermodynamic properties.

课程2
Quantum Mechanics

Course 2 of Statistical Thermodynamics presents an introduction to quantum mechanics at a level appropriate for those with mechanical or aerospace engineering backgrounds. Using a postulatory approach that describes the steps to follow, the Schrodinger wave equation is derived and simple solutions obtained that illustrate atomic and molecular structural behavior. More realistic behavior is also explored along with modern quantum chemistry numerical solution methods for solving the wave equation.

课程3
Ideal Gases

Course 3 of Statistical Thermodynamics, Ideal Gases, explores the behavior of systems when intermolecular forces are not important. This done by evaluating the appropriate partition functions for translational, rotational, vibrational and/or electronic motion. We start with pure ideal gases including monatomic, diatomic and polyatomic species. We then discuss both non-reacting and reacting ideal gas mixtures as both have many industrial applications. Computational methods for calculating equilibrium properties are introduced. We also discuss practical sources of ideal gas properties. Interestingly, in addition to normal low density gases, photons and electrons in metals can be described as though they are ideal gases and so we discuss them.

课程4
Dense Gases, Liquids and Solids

Course 4 of Statistical Thermodynamics addresses dense gases, liquids, and solids. As the density of a gas is increased, intermolecular forces begin to affect behavior. For small departures from ideal gas behavior, known as the dense gas limit, one can estimate the change in properties using the concept of a configuration integral, a modification to the partition function. This leads to the development of equations of state that are expansions in density from the ideal gas limit. Inter molecular potential energy functions are introduced and it is explored how they impact P-V-T behavior. As the density is increased, there is a transition to the liquid state. We explore whether this transition is smooth or abrupt by examining the stability of a thermodynamic system to small perturbations. We then present a brief discussion regarding the determination of the thermodynamic properties of liquids using concept of the radial distribution function (RDF), and how the function relates to thermodynamic properties. Finally, we explore two simple models of crystalline solids.

课程5
Non-Equilibrium Applications of Statistical Thermodynamics

Course 5 of Statistical Thermodynamics explores three different applications of non-equilibrium statistical thermodynamics. The first is the transport behavior of ideal gases, with some discussion of transport in dense gases and liquids. It starts with simple estimates of the transport properties of an ideas gas. It then introduces the Boltzmann Equation and describes the Chapman-Enskog solution of that equation in order to obtain the transport properties. It closes with a discussion of practical sources of transport properties. Spectroscopic methods have become increasingly common as a way of determining the thermodynamic state of a system. Here we present the underlying concepts of the subject and explores how spectroscopy can be used to determine thermodynamic and flow properties. Chemical kinetics are important in a variety of fluid/thermal applications including combustion, air quality, fuel cells and material processing. Here we cover the basics of chemical kinetics, with a particular focus on combustion. It starts with some definitions, including reaction rate and reaction rate constant. It then explores methods for determining reaction rate constants. Next, systems of reactions, or reaction mechanisms, are explored, including the oxidation of hydrogen and hydrocarbon fuels. Finally, computational tools for carrying out kinetic calculations are explored.

预备知识

U​ndergraduate Engineering Thermodynamics
B​.S. degree in mechanical, aerospace or chemical engineering.

Alibaba Cloud
声明:MOOC中国十分重视知识产权问题,我们发布之课程均源自下列机构,版权均归其所有,本站仅作报道收录并尊重其著作权益。感谢他们对MOOC事业做出的贡献!
  • Coursera
  • edX
  • OpenLearning
  • FutureLearn
  • iversity
  • Udacity
  • NovoEd
  • Canvas
  • Open2Study
  • Google
  • ewant
  • FUN
  • IOC-Athlete-MOOC
  • World-Science-U
  • Codecademy
  • CourseSites
  • opencourseworld
  • ShareCourse
  • gacco
  • MiriadaX
  • JANUX
  • openhpi
  • Stanford-Open-Edx
  • 网易云课堂
  • 中国大学MOOC
  • 学堂在线
  • 顶你学堂
  • 华文慕课
  • 好大学在线CnMooc
  • (部分课程由Coursera、Udemy、Linkshare共同提供)

© 2008-2019 MOOC.CN 慕课改变你,你改变世界